Chemical composition of Badenian brines from primary fluid inclusions in halite (Transcarpathian Basin, Ukraine)
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Keywords
Kłodawa Salt Dome, Stinking Shale, Main Dolomite, bitumen, biomarkers, source rock, hydrocarbons maturity
Abstract
The primary fluid inclusions, which may be helpful in detemining the chemical composition of brines in the Badenian evaporite basin, were found in the chevron halite crystals from the Transcarpathian Basin (Ukraine). Fluid inclusions in sedimentary halite were examined with the use of ultra-microchemical analysis. Concentration of brines was high - close to the middle stage of halite sedimentation. The content of ions: K+ ranged from 10.6 g/l to 17.6 g/l, Mg2+ from 31.4 g/l to 58.3 g/l, and SO4 2- from 22.4 g/l to 39.0 g/l. Based on the chemical composition of major ions it was concluded that the brine from the Transcarpathian basin was saturated (to the stage of halite crystallization) and was similar to the Badenian brines from other basins.
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References
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Dellwig L.F., 1955. Origin of the Salina salt of Michigan. Journal of Sedimentary Petrology, 25, 2, 83–110.
Eugster N.P., Harvie C.E. & Weare J.H., 1980. Mineral equilibria in the six-component seawoter system, Na-K-Mg-Ca-SO4-Cl-H2O, at 25 C. Geochimica et Cosmochimica Acta, 44, 1335–1347.
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Galamay A.R., 2010. Fiziko-khimichni umovi osadzhennya ta postsedimentatsiinoii perekristalizatsii badenskih solyeii ukraiinskogo peredkarpattya na dilyantsi Grinivka (za ridkimi vklyuchennyami u galiti). Gyeologiya i gyeohimiya goryuchih kopalin, 2, 64–77.
Galamay A.R., Bukowski K. & Przybyło J., 1997. Chemical composition and origin of brines in the Badenian evaporite basin of the Carpathian Fofedeep: fluid inclusion data from Wieliczka (Poland). Slovak Geological Magazine, 3, 165–171.
Galamay A.R. & Karoli S., 1997. Geochemistry of the Badenian salts from the East Slovakian Basin, Slovakia. Slovak Geological Magazine, 3, 187–192.
Galamay A.R., Bukowski K., Poberezhskyy A.V., Karoli S. & Kovalevich V.M., 2004. Origin of the Badenian salt from East Slovakłan basin indicated by based on the analysis of fluid inclusions. Annales Societatis Geologorum Poloniae, 74, 267–276.
Garlicki A., 1979. Sedymentacja soli mioceńskich w Polsce. Prace Geologiczne PAN, 119, 1–67.
Hardie L.A., 1996. Secular variations in seawater chemistry: An explanation for the coupled secular variation in the mineralogies of marine limestones and potash evaporates over the past 600 m.y. Geology, 24, 279–283.
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Korenevskii S.M., Zaharova V.M. & Shamahov V.A., 1977. Miotsenovye galogennye formatsii predgorii Karpat. Nedra
Kovalevich V.M., 1990. Galogenez i himicheskaya evolyutsiya okyeana v fanerozoe. Naukowa Dumka,
Kovalevich V.M., Galamay A.R. & Vovnyuk S., 2002. Genetichni tipi vklyuchen u galiti solenosnih formatsii Ukraini. Mineralogichni Zbirnik, 52, 146–151
Kovalevich V.M. & Petrichenko O. I., 1997. Chemical composition of brines in Miocene evaporite basins of Carpathian region. Slovak Geological Magazine, 3, 173–180.
Kovalevich V.M., 1997. ˛Inkluzje fluidalne w soli kamiennej z Bochni. Przegląd Geologiczny, 45, 822–825.
Kovalevych V.E. & Hauber L., 2000. Fluid inclusions in halite from the Middle Triassic salt deposits in northern Switzerland: evidence for seawater chemistry. 8th World Salt Symposium, 1, 143–148.
Kovalevych V.M., Carmona V., Pueyo J.J. & Peryt T.M., 2005. Ultramicrochemical Analyses (UMCA) and Cryogenic Scanning Electron Microscopy (Cryo-SEM-EDS) of brines in halite-hosted fluid inclusions: a comparative study of analytical data. Geochemistry International, 43, 268–276.
Lazar B. & Holland H., 1988. The analysis of fluid inclusions in halite. Geochimica et Cosmochimica Acta, 52, 485–490.
Lowenstein T.K. & Hardie L.A., 1985. Criteria for the recognition of salt-pan evaporites. Sedimentology, 32, 627–644.
Lowenstein T.K., Timofeeff M.N., Brennan S.T., Hardie L.A. & Demicco R.V., 2001. Oscillations in Phanerozoic seawater chemistry: Evidence from fluid inclusions. Science, 294, 1086–1088.
Lowenstein T.K., Hardie L.A., Timofeeff M.N. & Demicco R.V., 2003. Secular variation in seawater chemistry and the origin of calcium chloride basinal brines. Geology, 31, 857–860.
McCaffrey M.A., Lazar B. & Holland H.D., 1987. The evaporation path of seawater and the coprecipitatin of Br and K with halite. Journal of Sedimentary Petrology, 57, 928–937.
Peryt T.M., 2006. The beginning, development and termination of the Middle Miocene Badenian salinity crisis in Central Paratethys. Sedimentary Geology, 188–189, 379–396,
Petrichenko O.I., 1973. Metodi doslidzhennya vklyuchen u mineralah galogennih porid. Naukova Dumka, Kiev
Petrichenko O.I., 1988. Fiziko-himicheskie usloviya osadkoobrazovaniya v drevnih solerodnyh bassyeiinah. Naukova Dumka, Kiev
Petrichenko O.I., 1989. Epigenez ewaporitow. Naukova Dumka, Kiev,
Poberezhskiy A.V., 1991. Fiziko-himicheskie usloviya formirovaniya badensknh sulfatno- karbonatnyh otlozhenii Predkarpatya (v svyazi s ih seronosnostyu). Avtoref. dis. kand. gyeol.-min. nauk: 04.00.02 – gyeohimiya. IGGGI AN Ukrainy, Lvov
Poberezhskiy A.V. & Kovalevich V.M., 2001. Khimichnii sklad morskoi vodi v kainozoi (za rezultatami doslidzhennya vklyuchen u sedimentaitsiinomu galiti). Gyeologiya i gyeohimiyagoryuchih kopalin, 2, 90–109
Shaidetska V.S., 1997. The geochemistry of Neogene evaporites of Transcarpathian troughin Ukraine. Slovak Geological Magazine, 3, 193–200.
Sonnenfeld P., 1997. The Environment of Miocene Salt Basins in Cis- and Transcarpathia. Slovak Geological Magazine, 3, 83–90.
Timofeeff M.N., Lowenstein T.K. & Blackburn W.H., 2000. ESEM-EDS: an improved technique for major element chemical analyses of fluid inclusions. Chemical Geology, 164, 171–182.
Valyashko M.G., 1952. Galit, osnovnye yego raznosti, vstrechaemye v solyanyh ozerah, i ih struktura. Trudy VNII Galurgii, 23, 25–32
Valyashko M.G., 1962. Zakonomernosti formirovaniya mestorozhdenii solyei. Moskovskii Gosudarstvennyi Universitet, Moskva
Veigas J.G., Rossel L. & Garlickł A., 1997. Petrology and geochemistry (fluid inclusion) of Miocene halite rock salts (Badenian, Poland). Slovak Geological Magazine, 3, 181–186.
Zimmermann H., 2000. Tertiary seawater chemistry – implications from primary fluid inclusions in marine halite. American Journal of Science, 3000, 3–45.
Bukowski K., Czapowski G., Karoli S. & Bąbel M., 2007. Sedimentology and geochemistry of the Middle Miocene (Badenian) salt-bearing succession from East Slovakian Basin (Zbudza Formation). W: Schreiber B.C., Lugli S. & Bąbel M. (Eds), Evaporites Through Space and Time, Geological Society Special Publication, 285, 247–264.
Cendón D.I., Peryt T.M., Ayora C., Pueyo J.J. & Taberner C., 2004. The importance of recycling processes in the Middle Miocene Badenian evaporite basin (Carpathian foredeep): palaeoenvironmental implications. Palaeogeography, Palaeoclimatology, Palaeoecology, 212, 141–158.
Chruszczow D.P., 1980. Litologiya i gyeohimiya galogennyh formatsii Predkarpatskogo progiba. Naukova Dumka, Kiev.
Czapowski G., Bukowski K. & Poborska-Młynarska K., 2009. Mioceńskie sole kamienne i potasowe Zachodniej Ukrainy: seminarium geologiczno-górnicze PSGS nt. Złoża soli na kresach wschodnich dawnej Rzeczpospolitej. Geologia (kwartalnik AGH), 35, 3, 479–490.
Dellwig L.F., 1955. Origin of the Salina salt of Michigan. Journal of Sedimentary Petrology, 25, 2, 83–110.
Eugster N.P., Harvie C.E. & Weare J.H., 1980. Mineral equilibria in the six-component seawoter system, Na-K-Mg-Ca-SO4-Cl-H2O, at 25 C. Geochimica et Cosmochimica Acta, 44, 1335–1347.
Galamay A.R., 2001. Fiziko-chimichnii umovi formuvannya badenskih yevaporitovih vidkladiv Karpatskogo regionu. Avtoref. dis. kand. gyeol. nauk: 04.00.02 – gyeohimiya. IGGGK NAN Ukraini, Lviv.
Galamay A.R., 2006. Vklyuchennya z naftovoyu fazoyu u galiti badenskih yevaporitiv Karpatskogo regionu yak gyeohimichnii indikator naftogazonosnosti pidstilayuchih osadovih tovshch. Problemi gyeologii ta naftogazonosnosti Karpat: Tezi dop. Mizhnar. nauk. konf., Lviv, 54–57.
Galamay A.R., 2010. Fiziko-khimichni umovi osadzhennya ta postsedimentatsiinoii perekristalizatsii badenskih solyeii ukraiinskogo peredkarpattya na dilyantsi Grinivka (za ridkimi vklyuchennyami u galiti). Gyeologiya i gyeohimiya goryuchih kopalin, 2, 64–77.
Galamay A.R., Bukowski K. & Przybyło J., 1997. Chemical composition and origin of brines in the Badenian evaporite basin of the Carpathian Fofedeep: fluid inclusion data from Wieliczka (Poland). Slovak Geological Magazine, 3, 165–171.
Galamay A.R. & Karoli S., 1997. Geochemistry of the Badenian salts from the East Slovakian Basin, Slovakia. Slovak Geological Magazine, 3, 187–192.
Galamay A.R., Bukowski K., Poberezhskyy A.V., Karoli S. & Kovalevich V.M., 2004. Origin of the Badenian salt from East Slovakłan basin indicated by based on the analysis of fluid inclusions. Annales Societatis Geologorum Poloniae, 74, 267–276.
Garlicki A., 1979. Sedymentacja soli mioceńskich w Polsce. Prace Geologiczne PAN, 119, 1–67.
Hardie L.A., 1996. Secular variations in seawater chemistry: An explanation for the coupled secular variation in the mineralogies of marine limestones and potash evaporates over the past 600 m.y. Geology, 24, 279–283.
Horita J., Zimmermann H. & Holland H.D., 2002. Chemical evolution of seawater during the Phanerozoic: Implications from the record of marine evaporates. Geochimica et Cosmochimica Acta, 66, 3733–3756.
Kityk V.I., Bokun A.N., Panov G.M., Slivko Ye.P. & Shaidetskaya V.S., 1983. Galogennye formatsii Ukrainy: Zakarpatskii progib. Naukova Dumka, Kiev
Kityk V.I. & Petrichenko O.I., 1978. Vikoristannya vklyuchen u mineralah dlya zyasuvannya umov formuvannya naftogazovih rodovishch. Visnik AN URSR, 1, 55–60
Korenevskii S.M., Zaharova V.M. & Shamahov V.A., 1977. Miotsenovye galogennye formatsii predgorii Karpat. Nedra
Kovalevich V.M., 1990. Galogenez i himicheskaya evolyutsiya okyeana v fanerozoe. Naukowa Dumka,
Kovalevich V.M., Galamay A.R. & Vovnyuk S., 2002. Genetichni tipi vklyuchen u galiti solenosnih formatsii Ukraini. Mineralogichni Zbirnik, 52, 146–151
Kovalevich V.M. & Petrichenko O. I., 1997. Chemical composition of brines in Miocene evaporite basins of Carpathian region. Slovak Geological Magazine, 3, 173–180.
Kovalevich V.M., 1997. ˛Inkluzje fluidalne w soli kamiennej z Bochni. Przegląd Geologiczny, 45, 822–825.
Kovalevych V.E. & Hauber L., 2000. Fluid inclusions in halite from the Middle Triassic salt deposits in northern Switzerland: evidence for seawater chemistry. 8th World Salt Symposium, 1, 143–148.
Kovalevych V.M., Carmona V., Pueyo J.J. & Peryt T.M., 2005. Ultramicrochemical Analyses (UMCA) and Cryogenic Scanning Electron Microscopy (Cryo-SEM-EDS) of brines in halite-hosted fluid inclusions: a comparative study of analytical data. Geochemistry International, 43, 268–276.
Lazar B. & Holland H., 1988. The analysis of fluid inclusions in halite. Geochimica et Cosmochimica Acta, 52, 485–490.
Lowenstein T.K. & Hardie L.A., 1985. Criteria for the recognition of salt-pan evaporites. Sedimentology, 32, 627–644.
Lowenstein T.K., Timofeeff M.N., Brennan S.T., Hardie L.A. & Demicco R.V., 2001. Oscillations in Phanerozoic seawater chemistry: Evidence from fluid inclusions. Science, 294, 1086–1088.
Lowenstein T.K., Hardie L.A., Timofeeff M.N. & Demicco R.V., 2003. Secular variation in seawater chemistry and the origin of calcium chloride basinal brines. Geology, 31, 857–860.
McCaffrey M.A., Lazar B. & Holland H.D., 1987. The evaporation path of seawater and the coprecipitatin of Br and K with halite. Journal of Sedimentary Petrology, 57, 928–937.
Peryt T.M., 2006. The beginning, development and termination of the Middle Miocene Badenian salinity crisis in Central Paratethys. Sedimentary Geology, 188–189, 379–396,
Petrichenko O.I., 1973. Metodi doslidzhennya vklyuchen u mineralah galogennih porid. Naukova Dumka, Kiev
Petrichenko O.I., 1988. Fiziko-himicheskie usloviya osadkoobrazovaniya v drevnih solerodnyh bassyeiinah. Naukova Dumka, Kiev
Petrichenko O.I., 1989. Epigenez ewaporitow. Naukova Dumka, Kiev,
Poberezhskiy A.V., 1991. Fiziko-himicheskie usloviya formirovaniya badensknh sulfatno- karbonatnyh otlozhenii Predkarpatya (v svyazi s ih seronosnostyu). Avtoref. dis. kand. gyeol.-min. nauk: 04.00.02 – gyeohimiya. IGGGI AN Ukrainy, Lvov
Poberezhskiy A.V. & Kovalevich V.M., 2001. Khimichnii sklad morskoi vodi v kainozoi (za rezultatami doslidzhennya vklyuchen u sedimentaitsiinomu galiti). Gyeologiya i gyeohimiyagoryuchih kopalin, 2, 90–109
Shaidetska V.S., 1997. The geochemistry of Neogene evaporites of Transcarpathian troughin Ukraine. Slovak Geological Magazine, 3, 193–200.
Sonnenfeld P., 1997. The Environment of Miocene Salt Basins in Cis- and Transcarpathia. Slovak Geological Magazine, 3, 83–90.
Timofeeff M.N., Lowenstein T.K. & Blackburn W.H., 2000. ESEM-EDS: an improved technique for major element chemical analyses of fluid inclusions. Chemical Geology, 164, 171–182.
Valyashko M.G., 1952. Galit, osnovnye yego raznosti, vstrechaemye v solyanyh ozerah, i ih struktura. Trudy VNII Galurgii, 23, 25–32
Valyashko M.G., 1962. Zakonomernosti formirovaniya mestorozhdenii solyei. Moskovskii Gosudarstvennyi Universitet, Moskva
Veigas J.G., Rossel L. & Garlickł A., 1997. Petrology and geochemistry (fluid inclusion) of Miocene halite rock salts (Badenian, Poland). Slovak Geological Magazine, 3, 181–186.
Zimmermann H., 2000. Tertiary seawater chemistry – implications from primary fluid inclusions in marine halite. American Journal of Science, 3000, 3–45.
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Apr 1, 2011
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CZECHOWSKI, F., BURLIGA, S., & HOJNIAK, M. (2011). Chemical composition of Badenian brines from primary fluid inclusions in halite (Transcarpathian Basin, Ukraine). Geology, Geophysics and Environment, 37(2), 231. https://doi.org/10.7494/geol.2011.37.2.231
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